{"id":59,"date":"2012-11-29T21:00:53","date_gmt":"2012-11-29T21:00:53","guid":{"rendered":"http:\/\/pages.charlotte.edu\/craig-ogle\/?page_id=59"},"modified":"2013-03-28T15:49:53","modified_gmt":"2013-03-28T15:49:53","slug":"chiral-non-tranferable-ligands","status":"publish","type":"page","link":"https:\/\/pages.charlotte.edu\/craig-ogle\/research\/synthetic-method-development\/chiral-non-tranferable-ligands\/","title":{"rendered":"Chiral Non-Tranferable\u00a0Ligands"},"content":{"rendered":"<p>Chiral non-transferable ligands in the conjugate addition of organocuprates to enones<\/p>\n<p>We are exploring chiral nontransferable ligands for asymmetric reactions for \u03b1,\u03b2-unsaturated ketones and esters. We have used thienyls with a chiral arm and chiral N-silylamides as the chiral scaffolding and the non-transferable ligand.<br \/>\n<a href=\"http:\/\/pages.charlotte.edu\/craig-ogle\/wp-content\/uploads\/sites\/220\/2012\/11\/silylamides.gif\"><img decoding=\"async\" class=\"aligncenter size-full wp-image-30\" title=\"silylamides\" src=\"http:\/\/pages.charlotte.edu\/craig-ogle\/wp-content\/uploads\/sites\/220\/2012\/11\/silylamides.gif\" alt=\"\" width=\"500\" srcset=\"https:\/\/pages.charlotte.edu\/craig-ogle\/wp-content\/uploads\/sites\/220\/2012\/11\/silylamides.gif 711w, https:\/\/pages.charlotte.edu\/craig-ogle\/wp-content\/uploads\/sites\/220\/2012\/11\/silylamides-300x256.gif 300w\" sizes=\"(max-width: 711px) 100vw, 711px\" \/><\/a><br \/>\n<a href=\"http:\/\/pages.charlotte.edu\/craig-ogle\/wp-content\/uploads\/sites\/220\/2012\/11\/chiralthienyl.gif\"><img decoding=\"async\" class=\"aligncenter size-full wp-image-28\" title=\"chiralthienyl\" src=\"http:\/\/pages.charlotte.edu\/craig-ogle\/wp-content\/uploads\/sites\/220\/2012\/11\/chiralthienyl.gif\" alt=\"\" width=\"500\" srcset=\"https:\/\/pages.charlotte.edu\/craig-ogle\/wp-content\/uploads\/sites\/220\/2012\/11\/chiralthienyl.gif 1769w, https:\/\/pages.charlotte.edu\/craig-ogle\/wp-content\/uploads\/sites\/220\/2012\/11\/chiralthienyl-300x97.gif 300w, https:\/\/pages.charlotte.edu\/craig-ogle\/wp-content\/uploads\/sites\/220\/2012\/11\/chiralthienyl-1024x334.gif 1024w\" sizes=\"(max-width: 1769px) 100vw, 1769px\" \/><\/a><\/p>\n","protected":false},"excerpt":{"rendered":"<p>Chiral non-transferable ligands in the conjugate addition of organocuprates to enones We are exploring chiral nontransferable ligands for asymmetric reactions for \u03b1,\u03b2-unsaturated ketones and esters. We have used thienyls with a chiral arm and chiral N-silylamides as the chiral scaffolding and the non-transferable ligand.<\/p>\n","protected":false},"author":25,"featured_media":0,"parent":50,"menu_order":10,"comment_status":"closed","ping_status":"closed","template":"page-left-sidebar.php","meta":{"jetpack_post_was_ever_published":false,"footnotes":""},"class_list":["post-59","page","type-page","status-publish","hentry"],"jetpack_shortlink":"https:\/\/wp.me\/P2WtrN-X","jetpack_sharing_enabled":true,"_links":{"self":[{"href":"https:\/\/pages.charlotte.edu\/craig-ogle\/wp-json\/wp\/v2\/pages\/59","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/pages.charlotte.edu\/craig-ogle\/wp-json\/wp\/v2\/pages"}],"about":[{"href":"https:\/\/pages.charlotte.edu\/craig-ogle\/wp-json\/wp\/v2\/types\/page"}],"author":[{"embeddable":true,"href":"https:\/\/pages.charlotte.edu\/craig-ogle\/wp-json\/wp\/v2\/users\/25"}],"replies":[{"embeddable":true,"href":"https:\/\/pages.charlotte.edu\/craig-ogle\/wp-json\/wp\/v2\/comments?post=59"}],"version-history":[{"count":4,"href":"https:\/\/pages.charlotte.edu\/craig-ogle\/wp-json\/wp\/v2\/pages\/59\/revisions"}],"predecessor-version":[{"id":150,"href":"https:\/\/pages.charlotte.edu\/craig-ogle\/wp-json\/wp\/v2\/pages\/59\/revisions\/150"}],"up":[{"embeddable":true,"href":"https:\/\/pages.charlotte.edu\/craig-ogle\/wp-json\/wp\/v2\/pages\/50"}],"wp:attachment":[{"href":"https:\/\/pages.charlotte.edu\/craig-ogle\/wp-json\/wp\/v2\/media?parent=59"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}