A. Columbia University (1989-1994)
(1) “Hexakis(trimethylphosphine)tungsten(0): Synthesis, Structure, and Reactivity” Rabinovich, D.; Parkin, G. J. Am. Chem. Soc. 1990, 112, 5381-5383.
(2) “Competitive sp3 and sp2 C-H Bond Activation of Phenols by W(PMe3)6 and W(PMe3)4(h2-CH2PMe2)H: Formation of Four- and Five-Membered Oxametallacycles” Rabinovich, D.; Zelman, R.; Parkin, G. J. Am. Chem. Soc. 1990, 112, 9632-9633.
(3) “The Syntheses, Structures, and Reactivity of Monomeric Tungsten(IV) and Tungsten(VI) Bis(sulfido) Complexes: Facile Elimination of H2 from H2S” Rabinovich, D.; Parkin, G. J. Am. Chem. Soc. 1991, 113, 5904-5905.
(4) “Synthesis and Structure of W(PMe3)4(Te)2: The First Transition-Metal Complex with a Terminal Tellurido Ligand” Rabinovich, D.; Parkin, G. J. Am. Chem. Soc. 1991, 113, 9421-9422.
(5) “Synthetic, Structural, and Mechanistic Studies of the C-H Bond Activation of Phenols by W(PMe3)6 and W(PMe3)4(h2‑CH2PMe2)H” Rabinovich, D.; Zelman, R.; Parkin, G. J. Am. Chem. Soc. 1992, 114, 4611-4621.
(6) “A Mechanistic Study of the Oxidative-Addition of H2 to W(PMe3)4I2: Observation of an Inverse Equilibrium Isotope Effect” Rabinovich, D.; Parkin, G. J. Am. Chem. Soc. 1993, 115, 353-354.
(7) “Isocyanide-Induced Coupling of Terminal Tellurido Ligands: The Synthesis and Structure of W(PMe3)(CNBut)4(h2-Te2)” Rabinovich, D.; Parkin, G. J. Am. Chem. Soc. 1993, 115, 9822-9823.
(8) “Syntheses, Structures, and Reactivities of Terminal Selenido Complexes of Tungsten” Rabinovich, D.; Parkin, G. Inorg. Chem. 1994, 33, 2313-2314.
(9) “Oxidative-Cleavage of the Te-Te Bond in h2‑Ditellurido Complexes: Syntheses and Structures of M(PMe3)4(h2-Te2)H2 (M = Mo, W)” Murphy, V. J.; Rabinovich, D.; Parkin, G. J. Chem. Soc., Chem. Commun. 1995, 1099-1100.
(10) “False Minima and the Perils of a Polar Axis in X-ray Structure Solutions: Molecular Structures of W(PMe3)4H2X2 (X = F, Cl, Br) and W(PMe3)4H2F2(H2O)” Murphy, V. J.; Rabinovich, D.; Parkin, G. J. Am. Chem. Soc. 1995, 117, 9762-9763.
See also: C & E News 1995, 73 (40), 27-29.
(11) “Terminal Sulfido, Selenido, and Tellurido Complexes of Tungsten” Rabinovich, D.; Parkin, G. Inorg. Chem. 1995, 34, 6341-6361.
(12) “False Minima in X-ray Structure Solutions Associated with a ‘Partial Polar Ambiguity’: Single Crystal X-ray and Neutron Diffraction Studies on the Eight-Coordinate Tungsten Hydride Complexes, W(PMe3)4H2X2 (X = F, Cl, Br, I) and W(PMe3)4H2F(FHF)” Murphy, V. J.; Rabinovich, D.; Hascall, T.; Klooster, W. T.; Koetzle, T. F.; Parkin, G. J. Am. Chem. Soc. 1998, 120, 4372-4387.
(13) “Mechanistic and Theoretical Analysis of the Oxidative Addition of H2 to Six‑Coordinate Molybdenum and Tungsten Complexes M(PMe3)4X2 (M = Mo, W; X = F, Cl, Br, I): An Inverse Equilibrium Isotope Effect and an Unprecedented Halide Dependance” Hascall, T.; Rabinovich, D.; Murphy, V. J.; Beachy, M. D.; Friesner, R. A.; Parkin, G. J. Am. Chem. Soc. 1999, 121, 11402-11417.
B. Los Alamos National Laboratory (1994-1996)
(14) “New Dicarbollide Complexes of Uranium” Rabinovich, D.; Haswell, C. M.; Scott, B. L.; Miller, R. L.; Nielsen, J. B.; Abney, K. D. Inorg. Chem. 1996, 35, 1425-1426.
(15) “Tetrachlorobis(N,N,N’,N’-tetramethylenediamine-N,N’)thorium(IV)” Rabinovich, D.; Schimek, G. L.; Pennington, W. T.; Nielsen, J. B.; Abney, K. D. Acta Crystallogr. 1997, C53, 191-193.
(16) “Synthesis of [Li(THF)4]2[Th(h2-C2B9H11)2X2] (X = Cl, Br, I): the First Dicarbollide Complexes of Thorium” Rabinovich, D.; Chamberlin, R. M.; Scott, B. L.; Nielsen, J. B.; Abney, K. D. Inorg. Chem. 1997, 36, 4216-4217.
(17) “Dibromobis(h5-pentamethylcyclopentadienyl)thorium(IV)” Rabinovich, D.; Schimek, G. L.; Pennington, W. T.; Nielsen, J. B.; Abney, K. D. Acta Crystallogr. 1997, C53, 1794-1797.
(18) “Trimethylsilyl Iodide as a Halide Exchange Reagent in Inorganic Chemistry: Synthesis and Structure of Cp*2ThI2 (Cp* = h5-C5Me5)” Rabinovich, D.; Bott, S. G.; Nielsen, J. B.; Abney, K. D. Inorg. Chim. Acta. 1998, 274, 232-235.
(19) “Octaaquabromouranium(IV) Tribromide Monohydrate, [UBr(H2O)8]Br3.H2O” Rabinovich, D.; Schimek, G. L.; Pennington, W. T.; Nielsen, J. B.; Abney, K. D. Acta Crystallogr. 1998, C54, 1740-1742.
(20) “Molecular Structure of ThBr4(DME)2 (DME = 1,2-dimethoxyethane)” Rabinovich, D.; Scott, B. L.; Nielsen, J. B.; Abney, K. D. J. Chem. Crystallogr. 1999, 29, 243-246.
C. UNC Charlotte (1996-)
(21) “Methyltris(pyrazolyl)silanes: New Tripodal Nitrogen-Donor Ligands” Pullen, E. E.; Rheingold, A. L.; Rabinovich, D. Inorg. Chem. Commun. 1999, 2, 194-196.
(22) “Tris[(alkylthio)methyl]silanes: Syntheses and Structures of Chromium, Molybdenum, and Tungsten Complexes with a Tripodal Thioether Ligand” Yim, H. W.; Tran, L. M.; Dobbin, E. D.; Rabinovich, D.; Liable-Sands, L. M.; Incarvito, C. D.; Lam, K.‑C.; Rheingold, A. L. Inorg. Chem. 1999, 38, 2211-2215.
(23) “One-Dimensional Copper(I) Coordination Polymers Based on a Tridentate Thioether Ligand” Yim, H. W.; Tran, L. M.; Pullen, E. E.; Rabinovich, D.; Liable-Sands, L. M.; Concolino, T. E.; Rheingold, A. L. Inorg. Chem. 1999, 38, 6234-6239.
(24) “Metallurgy in the Laboratory: Preparation of Pure Antimony” O’Klatner, B. L.; Rabinovich, D. J. Chem. Educ. 2000, 77, 251-252.
(25) “Syntheses and Structures of Methyltris(pyrazolyl)silane Complexes of the Group 6 Metals” Pullen, E. E.; Rabinovich, D.; Incarvito, C. D.; Concolino, T. E.; Rheingold, A. L. Inorg. Chem. 2000, 39, 1561-1567.
(26) “Bismuth(III) Thioether Chemistry: Synthesis and Structure of a Coordination Polymer Derived from BiCl3 and MeSi(CH2SMe)3” Yim, H. W.; Lam. K.‑C.; Rheingold, A. L.; Rabinovich, D. Polyhedron 2000, 19, 849-853.
(27) “Synthesis and Structure of {h3-MeSi(CH2SPh)3}Cr(CO)3: How Long Can a Cr(0)—S(thioether) Bond Length Be?” Blackwell III, W. C.; Bunich, D.; Concolino, T. E.; Rheingold, A. L.; Rabinovich, D. Inorg. Chem. Commun. 2000, 3, 325-327.
(28) “Zinc Bis(pyrazolyl)silane Complexes” Richburg, L. M.; Farouq, J. A.; Incarvito, C. D.; Rheingold, A. L.; Rabinovich, D. Polyhedron 2000, 19, 1815-1820.
(29) “Synthesis and Characterization of Two New Bulky Tris(mercaptoimidazolyl)borate Ligands and their Zinc and Cadmium Complexes” Bakbak, S.; Bhatia, V. K.; Incarvito, C. D.; Rheingold, A. L.; Rabinovich, D. Polyhedron 2001, 20, 3343-3348.
(30) “Modeling Nickel Hydrogenases: Synthesis and Structure of a Distorted Octahedral Complex with an Unprecedented [NiS4H2] Core” Alvarez, H. M.; Krawiec, M.; Donovan‑Merkert, B. T.; Fouzi, M.; Rabinovich, D. Inorg. Chem. 2001, 40, 5736-5737.
(31) “Synthesis and Characterization of Novel Mononuclear Cadmium Thiolate Complexes in a Sulfur-Rich Environment” Bakbak, S.; Incarvito, C. D.; Rheingold, A. L.; Rabinovich, D. Inorg. Chem. 2002, 41, 998-1001.
(32) “Novel Spherical Assembly of Gold Nanoparticles Mediated by a Tetradentate Thioether” Maye, M. M.; Chun, S. C.; Rabinovich, D.; Zhong, C.‑J. J. Am. Chem. Soc. 2002, 124, 4958-4959.
(33) “Bulky Tris(mercaptoimidazolyl)borates: Synthesis and Molecular Structures of the Group 12 Metal Complexes (TmtBu)MBr (M = Zn, Cd, Hg)” White, J. L.; Tanski, J. M.; Rabinovich, D. J. Chem. Soc., Dalton Trans. 2002, 2987-2991.
(34) “[Bis(2-mercapto-1-methylimidazol-3-yl)borato](triphenylphosphine)gold(I)” Mohamed, A. A.; Rabinovich, D.; Fackler, J. P. Acta Crystallogr. 2002, E58, m726-m727.
(35) “Construction of Spherical Assembly of Gold Nanoparticles Using Tetra[(methylthio)methyl]silane as Ligand” Maye, M. M.; Lim, I.-I. S.; Luo, J.; Han, L.; Rabinovich, D.; Chen, S.; Maye, M. P.; Zhong, C.‑J. Mat. Res. Soc. Symp. Proc. 2003, 739, H2.6.1-H2.6.6.
(36) “Homoleptic Group 12 Metal Bis(mercaptoimidazolyl)borate Complexes M[BmR]2 (M = Zn, Cd, Hg)” Alvarez, H. M.; Tran, T. B.; Richter, M. A.; Alyounes, D. M.; Rabinovich, D.; Tanski, J. M.; Krawiec, M. Inorg. Chem. 2003, 42, 2149-2156.
(37) “Synthesis and Structural Characterization of 2-mercapto-1‑tert‑butylimidazole and its Group 12 Metal Derivatives (HmimtBu)2MBr2 (M = Zn, Cd, Hg)” White, J. L.; Tanski, J. M.; Churchill, D. G.; Rheingold, A. L.; Rabinovich, D. J. Chem. Crystallogr. 2003, 33, 437-445.
(38) “cis-Dichlorotetrakis(2-mercapto-1-tert-butylimidazole)lead(II)” Evans, R. N.; Mihalcik, D. J.; Rabinovich, D.; Jones, D. S. Acta Crystallogr. 2003, E59, m370-m372.
(39) “Size-Controlled Assembly of Gold Nanoparticles Induced by a Tridentate Thioether Ligand” Maye, M. M.; Luo, J.; Lim, I.‑I. S.; Han, L.; Kariuki, N. N.; Rabinovich, D.; Liu, T.; Zhong, C.‑J. J. Am. Chem. Soc. 2003, 125, 9906-9907.
(40) “Di‑m‑iodo‑bis{[methyltris(methylthio)methyl]silane‑k2S,S’]copper(I)}” Yim, H. W.; Rabinovich, D.; Lam, K.‑C.; Golen, J. A.; Rheingold, A. L. Acta Crystallogr. 2003, E59, m556-m558.
(41) “Bis(mercaptoimidazolyl)borates and the Control of Nuclearity in Cadmium Thiolate Complexes” Philson, L. A.; Alyounes, D. M.; Zakharov, L. N.; Rheingold, A. L.; Rabinovich, D. Polyhedron 2003, 22, 3461-3466.
(42) “Poly(mercaptoimidazolyl)borate chemistry and the predominance of k3‑S,S,H over k2‑S,S or k3‑S,S,S coordination modes: unexpected formation of square pyramidal Ni(II) complexes” Alvarez, H. M.; Tanski, J. M.; Rabinovich, D. Polyhedron 2004, 23, 395-403.
(43) “Thallium Bis(mercaptoimidazolyl)borates” Alvarez, H. M.; Gillespie, P. A.; Gause, C. D.; Rheingold, A. L.; Golen, J. A.; Rabinovich, D. Polyhedron 2004, 23, 617-622.
(44) “Cobalt Tris(mercaptoimidazolyl)borate Complexes: Synthetic Studies and the Structure of the First Cobaltaboratrane” Mihalcik, D. J.; White, J. L.; Tanski, J. M.; Zakharov, L. N.; Yap, G. P. A.; Incarvito, C. D.; Rheingold, A. L.; Rabinovich, D. Dalton Trans. 2004, 1626-1634.
(45) “Manganese(I) Poly(mercaptoimidazolyl)borate Complexes: Spectroscopic and Structural Characterization of Mn…H—B Interactions in Solution and in the Solid State” Graham, L. A.; Fout, A. R.; Kuehne, K. R.; White, J. L.; Marks, F. M.; Yap, G. P. A.; Zakharov, L. N.; Rheingold, A. L.; Rabinovich, D. Dalton Trans. 2005, 171-180.
(46) “Mediator–Template Assembly of Nanoparticles” Maye, M. M.; Lim, I.‑I. S.; Luo, J.; Rab, Z.; Rabinovich, D.; Liu, T.; Zhong, C.‑J. J. Am. Chem. Soc. 2005, 127, 1519-1529.
(47) “Formation of Extended 1D Coordination Polymers in Tetrathioether Complexes of Mercury(II): Effect of the Organic Substituents on the Crystal Structures of {Si(CH2SR)4}HgBr2 (R = Me, Ph)” Peindy, H. N.; Guyon, F.; Knorr, M.; Smith, A. B.; Farouq, J. A.; Islas, S. A.; Rabinovich, D.; Golen, J. A.; Strohmann, C. Inorg. Chem. Commun. 2005, 8, 479-482.
(48) “Tris(mercaptoimidazolyl)borate Complexes of the Coinage Metals: Syntheses and Molecular Structures of the First Gold Compounds and Related Copper and Silver Derivatives” Patel, D. V.; Mihalcik, D. J.; Kreisel, K. A.; Yap, Glenn P. A.; Zakharov, L. N.; Kassel, W. S.; Rheingold, A. L.; Rabinovich, D. Dalton Trans. 2005, 2410-2416.
(49) “Poly(mercaptoimidazolyl)borate Complexes of Cadmium and Mercury” Rabinovich, D. Struct. Bond. 2006, 120, 143-162.
(50) “[Bis(3‑methyl‑2-thioxo‑2,3‑dihydro‑1H‑imidazolyl)borato‑k2S,S’]dibromoindium(III)” Hill, S. C.; Jones, D. S.; Rabinovich, D. Acta Crystallogr. 2006, E62, m702-m704.
(51) “Growth and Optical Properties of Wurtzite-Type CdS Nanocrystals” Cao, H.; Wang, G.; Zhang, S.; Zhang, X.; Rabinovich, D. Inorg. Chem. 2006, 45, 5103-5108.
(52) “Gold(I) Tris(mercaptoimidazolyl)borate Chemistry: Synthesis and Molecular Structure of the First Trinuclear TmR Complex of a Transition Metal” Patel, D. V.; Kreisel, K. A.; Yap, G. P. A.; Rabinovich, D. Inorg. Chem. Commun. 2006, 9, 748-750.
(53) “Generation and Optical Properties of Monodisperse Wurtzite-Type ZnS Microspheres” Wu, Q.; Cao, H.; Zhang, S.; Zhang, X.; Rabinovich, D. Inorg. Chem. 2006, 45, 7316-7322.
(54) “General Classification of Organometallic Reactions” Rabinovich, D. In Comprehensive Organometallic Chemistry III; Crabtree, R. H., Mingos, D. M. P., Eds.; Elsevier: Oxford, 2007; Vol. 1, Chapter 1.03, pp 93-118.
(55) “Nickel Nitrosyl Complexes in a Sulfur-Rich Environment: the First Poly(mercapto-imidazolyl)borate Derivatives” Maffett, L. S.; Gunter, K. L.; Kreisel, K. A.; Yap, G. P. A.; Rabinovich, D. Polyhedron 2007, 26, 4758-4764.
(56) “Lead(II) in a Sulfur-Rich Environment: Synthesis and Molecular Structure of the First Dinuclear Bis(mercaptoimidazolyl)methane Complex” Pinder, T. A.; VanDerveer, D.; Rabinovich, D. Inorg. Chem. Commun. 2007, 10, 1381-1384.
(57) “Femtosecond Isomerization in a Photochromic Molecular Switch” Mockus, N. V.; Rabinovich, D.; Petersen, J. L.; Rack, J. J. Angew. Chem. Int. Ed., in press.
Last updated: 19 December 2007