A. Columbia University (1989-1994)<\/p>\n
(1) \u201cHexakis(trimethylphosphine)tungsten(0): Synthesis, Structure, and Reactivity\u201d Rabinovich, D.; Parkin, G. J. Am. Chem. Soc. 1990, 112, 5381-5383.<\/p>\n
(2) \u201cCompetitive sp3 and sp2 C-H Bond Activation of Phenols by W(PMe3)6 and W(PMe3)4(h2-CH2PMe2)H: Formation of Four- and Five-Membered Oxametallacycles\u201d Rabinovich, D.; Zelman, R.; Parkin, G. J. Am. Chem. Soc. 1990, 112, 9632-9633.<\/p>\n
(3) \u201cThe Syntheses, Structures, and Reactivity of Monomeric Tungsten(IV) and Tungsten(VI) Bis(sulfido) Complexes: Facile Elimination of H2 from H2S\u201d Rabinovich, D.; Parkin, G. J. Am. Chem. Soc. 1991, 113, 5904-5905.<\/p>\n
(4) \u201cSynthesis and Structure of W(PMe3)4(Te)2: The First Transition-Metal Complex with a Terminal Tellurido Ligand\u201d Rabinovich, D.; Parkin, G. J. Am. Chem. Soc. 1991, 113, 9421-9422.<\/p>\n
(5) \u201cSynthetic, Structural, and Mechanistic Studies of the C-H Bond Activation of Phenols by W(PMe3)6 and W(PMe3)4(h2\u2011CH2PMe2)H\u201d Rabinovich, D.; Zelman, R.; Parkin, G. J. Am. Chem. Soc. 1992, 114, 4611-4621.<\/p>\n
(6) \u201cA Mechanistic Study of the Oxidative-Addition of H2 to W(PMe3)4I2: Observation of an Inverse Equilibrium Isotope Effect\u201d Rabinovich, D.; Parkin, G. J. Am. Chem. Soc. 1993, 115, 353-354.<\/p>\n
(7) \u201cIsocyanide-Induced Coupling of Terminal Tellurido Ligands: The Synthesis and Structure of W(PMe3)(CNBut)4(h2-Te2)\u201d Rabinovich, D.; Parkin, G. J. Am. Chem. Soc. 1993, 115, 9822-9823.<\/p>\n
(8) \u201cSyntheses, Structures, and Reactivities of Terminal Selenido Complexes of Tungsten\u201d Rabinovich, D.; Parkin, G. Inorg. Chem. 1994, 33, 2313-2314.<\/p>\n
(9) \u201cOxidative-Cleavage of the Te-Te Bond in h2\u2011Ditellurido Complexes: Syntheses and Structures of M(PMe3)4(h2-Te2)H2 (M = Mo, W)\u201d Murphy, V. J.; Rabinovich, D.; Parkin, G. J. Chem. Soc., Chem. Commun. 1995, 1099-1100.<\/p>\n
(10) \u201cFalse Minima and the Perils of a Polar Axis in X-ray Structure Solutions: Molecular Structures of W(PMe3)4H2X2 (X = F, Cl, Br) and W(PMe3)4H2F2(H2O)\u201d Murphy, V. J.; Rabinovich, D.; Parkin, G. J. Am. Chem. Soc. 1995, 117, 9762-9763.
\nSee also: C & E News 1995, 73 (40), 27-29.<\/p>\n
(11) \u201cTerminal Sulfido, Selenido, and Tellurido Complexes of Tungsten\u201d Rabinovich, D.; Parkin, G. Inorg. Chem. 1995, 34, 6341-6361.<\/p>\n
(12) \u201cFalse Minima in X-ray Structure Solutions Associated with a \u2018Partial Polar Ambiguity\u2019: Single Crystal X-ray and Neutron Diffraction Studies on the Eight-Coordinate Tungsten Hydride Complexes, W(PMe3)4H2X2 (X = F, Cl, Br, I) and W(PMe3)4H2F(FHF)\u201d Murphy, V. J.; Rabinovich, D.; Hascall, T.; Klooster, W. T.; Koetzle, T. F.; Parkin, G. J. Am. Chem. Soc. 1998, 120, 4372-4387.<\/p>\n
(13) \u201cMechanistic and Theoretical Analysis of the Oxidative Addition of H2 to Six\u2011Coordinate Molybdenum and Tungsten Complexes M(PMe3)4X2 (M = Mo, W; X = F, Cl, Br, I): An Inverse Equilibrium Isotope Effect and an Unprecedented Halide Dependance\u201d Hascall, T.; Rabinovich, D.; Murphy, V. J.; Beachy, M. D.; Friesner, R. A.; Parkin, G. J. Am. Chem. Soc. 1999, 121, 11402-11417.<\/p>\n
B. Los Alamos National Laboratory (1994-1996)<\/p>\n
(14) \u201cNew Dicarbollide Complexes of Uranium\u201d Rabinovich, D.; Haswell, C. M.; Scott, B. L.; Miller, R. L.; Nielsen, J. B.; Abney, K. D. Inorg. Chem. 1996, 35, 1425-1426.<\/p>\n
(15) \u201cTetrachlorobis(N,N,N\u2019,N\u2019-tetramethylenediamine-N,N\u2019)thorium(IV)\u201d Rabinovich, D.; Schimek, G. L.; Pennington, W. T.; Nielsen, J. B.; Abney, K. D. Acta Crystallogr. 1997, C53, 191-193.<\/p>\n
(16) \u201cSynthesis of [Li(THF)4]2[Th(h2-C2B9H11)2X2] (X = Cl, Br, I): the First Dicarbollide Complexes of Thorium\u201d Rabinovich, D.; Chamberlin, R. M.; Scott, B. L.; Nielsen, J. B.; Abney, K. D. Inorg. Chem. 1997, 36, 4216-4217.<\/p>\n
(17) \u201cDibromobis(h5-pentamethylcyclopentadienyl)thorium(IV)\u201d Rabinovich, D.; Schimek, G. L.; Pennington, W. T.; Nielsen, J. B.; Abney, K. D. Acta Crystallogr. 1997, C53, 1794-1797.<\/p>\n
(18) \u201cTrimethylsilyl Iodide as a Halide Exchange Reagent in Inorganic Chemistry: Synthesis and Structure of Cp*2ThI2 (Cp* = h5-C5Me5)\u201d Rabinovich, D.; Bott, S. G.; Nielsen, J. B.; Abney, K. D. Inorg. Chim. Acta. 1998, 274, 232-235.<\/p>\n
(19) \u201cOctaaquabromouranium(IV) Tribromide Monohydrate, [UBr(H2O)8]Br3.H2O\u201d Rabinovich, D.; Schimek, G. L.; Pennington, W. T.; Nielsen, J. B.; Abney, K. D. Acta Crystallogr. 1998, C54, 1740-1742.<\/p>\n
(20) \u201cMolecular Structure of ThBr4(DME)2 (DME = 1,2-dimethoxyethane)\u201d Rabinovich, D.; Scott, B. L.; Nielsen, J. B.; Abney, K. D. J. Chem. Crystallogr. 1999, 29, 243-246.<\/p>\n
C. UNC Charlotte (1996-)<\/p>\n
(21) \u201cMethyltris(pyrazolyl)silanes: New Tripodal Nitrogen-Donor Ligands\u201d Pullen, E. E.; Rheingold, A. L.; Rabinovich, D. Inorg. Chem. Commun. 1999, 2, 194-196.<\/p>\n
(22) \u201cTris[(alkylthio)methyl]silanes: Syntheses and Structures of Chromium, Molybdenum, and Tungsten Complexes with a Tripodal Thioether Ligand\u201d Yim, H. W.; Tran, L. M.; Dobbin, E. D.; Rabinovich, D.; Liable-Sands, L. M.; Incarvito, C. D.; Lam, K.\u2011C.; Rheingold, A. L. Inorg. Chem. 1999, 38, 2211-2215.<\/p>\n
(23) \u201cOne-Dimensional Copper(I) Coordination Polymers Based on a Tridentate Thioether Ligand\u201d Yim, H. W.; Tran, L. M.; Pullen, E. E.; Rabinovich, D.; Liable-Sands, L. M.; Concolino, T. E.; Rheingold, A. L. Inorg. Chem. 1999, 38, 6234-6239.<\/p>\n
(24) \u201cMetallurgy in the Laboratory: Preparation of Pure Antimony\u201d O\u2019Klatner, B. L.; Rabinovich, D. J. Chem. Educ. 2000, 77, 251-252.<\/p>\n
(25) \u201cSyntheses and Structures of Methyltris(pyrazolyl)silane Complexes of the Group 6 Metals\u201d Pullen, E. E.; Rabinovich, D.; Incarvito, C. D.; Concolino, T. E.; Rheingold, A. L. Inorg. Chem. 2000, 39, 1561-1567.<\/p>\n
(26) \u201cBismuth(III) Thioether Chemistry: Synthesis and Structure of a Coordination Polymer Derived from BiCl3 and MeSi(CH2SMe)3\u201d Yim, H. W.; Lam. K.\u2011C.; Rheingold, A. L.; Rabinovich, D. Polyhedron 2000, 19, 849-853.<\/p>\n
(27) \u201cSynthesis and Structure of {h3-MeSi(CH2SPh)3}Cr(CO)3: How Long Can a Cr(0)\u2014S(thioether) Bond Length Be?\u201d Blackwell III, W. C.; Bunich, D.; Concolino, T. E.; Rheingold, A. L.; Rabinovich, D. Inorg. Chem. Commun. 2000, 3, 325-327.<\/p>\n
(28) \u201cZinc Bis(pyrazolyl)silane Complexes\u201d Richburg, L. M.; Farouq, J. A.; Incarvito, C. D.; Rheingold, A. L.; Rabinovich, D. Polyhedron 2000, 19, 1815-1820.<\/p>\n
(29) \u201cSynthesis and Characterization of Two New Bulky Tris(mercaptoimidazolyl)borate Ligands and their Zinc and Cadmium Complexes\u201d Bakbak, S.; Bhatia, V. K.; Incarvito, C. D.; Rheingold, A. L.; Rabinovich, D. Polyhedron 2001, 20, 3343-3348.<\/p>\n
(30) \u201cModeling Nickel Hydrogenases: Synthesis and Structure of a Distorted Octahedral Complex with an Unprecedented [NiS4H2] Core\u201d Alvarez, H. M.; Krawiec, M.; Donovan\u2011Merkert, B. T.; Fouzi, M.; Rabinovich, D. Inorg. Chem. 2001, 40, 5736-5737.<\/p>\n
(31) \u201cSynthesis and Characterization of Novel Mononuclear Cadmium Thiolate Complexes in a Sulfur-Rich Environment\u201d Bakbak, S.; Incarvito, C. D.; Rheingold, A. L.; Rabinovich, D. Inorg. Chem. 2002, 41, 998-1001.<\/p>\n
(32) \u201cNovel Spherical Assembly of Gold Nanoparticles Mediated by a Tetradentate Thioether\u201d Maye, M. M.; Chun, S. C.; Rabinovich, D.; Zhong, C.\u2011J. J. Am. Chem. Soc. 2002, 124, 4958-4959.<\/p>\n
(33) \u201cBulky Tris(mercaptoimidazolyl)borates: Synthesis and Molecular Structures of the Group 12 Metal Complexes (TmtBu)MBr (M = Zn, Cd, Hg)\u201d White, J. L.; Tanski, J. M.; Rabinovich, D. J. Chem. Soc., Dalton Trans. 2002, 2987-2991.<\/p>\n
(34) \u201c[Bis(2-mercapto-1-methylimidazol-3-yl)borato](triphenylphosphine)gold(I)\u201d Mohamed, A. A.; Rabinovich, D.; Fackler, J. P. Acta Crystallogr. 2002, E58, m726-m727.<\/p>\n
(35) \u201cConstruction of Spherical Assembly of Gold Nanoparticles Using Tetra[(methylthio)methyl]silane as Ligand\u201d Maye, M. M.; Lim, I.-I. S.; Luo, J.; Han, L.; Rabinovich, D.; Chen, S.; Maye, M. P.; Zhong, C.\u2011J. Mat. Res. Soc. Symp. Proc. 2003, 739, H2.6.1-H2.6.6.<\/p>\n
(36) \u201cHomoleptic Group 12 Metal Bis(mercaptoimidazolyl)borate Complexes M[BmR]2 (M = Zn, Cd, Hg)\u201d Alvarez, H. M.; Tran, T. B.; Richter, M. A.; Alyounes, D. M.; Rabinovich, D.; Tanski, J. M.; Krawiec, M. Inorg. Chem. 2003, 42, 2149-2156.<\/p>\n
(37) \u201cSynthesis and Structural Characterization of 2-mercapto-1\u2011tert\u2011butylimidazole and its Group 12 Metal Derivatives (HmimtBu)2MBr2 (M = Zn, Cd, Hg)\u201d White, J. L.; Tanski, J. M.; Churchill, D. G.; Rheingold, A. L.; Rabinovich, D. J. Chem. Crystallogr. 2003, 33, 437-445.<\/p>\n
(38) \u201ccis-Dichlorotetrakis(2-mercapto-1-tert-butylimidazole)lead(II)\u201d Evans, R. N.; Mihalcik, D. J.; Rabinovich, D.; Jones, D. S. Acta Crystallogr. 2003, E59, m370-m372.<\/p>\n
(39) \u201cSize-Controlled Assembly of Gold Nanoparticles Induced by a Tridentate Thioether Ligand\u201d Maye, M. M.; Luo, J.; Lim, I.\u2011I. S.; Han, L.; Kariuki, N. N.; Rabinovich, D.; Liu, T.; Zhong, C.\u2011J. J. Am. Chem. Soc. 2003, 125, 9906-9907.<\/p>\n
(40) \u201cDi\u2011m\u2011iodo\u2011bis{[methyltris(methylthio)methyl]silane\u2011k2S,S\u2019]copper(I)}\u201d Yim, H. W.; Rabinovich, D.; Lam, K.\u2011C.; Golen, J. A.; Rheingold, A. L. Acta Crystallogr. 2003, E59, m556-m558.<\/p>\n
(41) \u201cBis(mercaptoimidazolyl)borates and the Control of Nuclearity in Cadmium Thiolate Complexes\u201d Philson, L. A.; Alyounes, D. M.; Zakharov, L. N.; Rheingold, A. L.; Rabinovich, D. Polyhedron 2003, 22, 3461-3466.<\/p>\n
(42) \u201cPoly(mercaptoimidazolyl)borate chemistry and the predominance of k3\u2011S,S,H over k2\u2011S,S or k3\u2011S,S,S coordination modes: unexpected formation of square pyramidal Ni(II) complexes\u201d Alvarez, H. M.; Tanski, J. M.; Rabinovich, D. Polyhedron 2004, 23, 395-403.<\/p>\n
(43) \u201cThallium Bis(mercaptoimidazolyl)borates\u201d Alvarez, H. M.; Gillespie, P. A.; Gause, C. D.; Rheingold, A. L.; Golen, J. A.; Rabinovich, D. Polyhedron 2004, 23, 617-622.<\/p>\n
(44) \u201cCobalt Tris(mercaptoimidazolyl)borate Complexes: Synthetic Studies and the Structure of the First Cobaltaboratrane\u201d Mihalcik, D. J.; White, J. L.; Tanski, J. M.; Zakharov, L. N.; Yap, G. P. A.; Incarvito, C. D.; Rheingold, A. L.; Rabinovich, D. Dalton Trans. 2004, 1626-1634.<\/p>\n
(45) \u201cManganese(I) Poly(mercaptoimidazolyl)borate Complexes: Spectroscopic and Structural Characterization of Mn\u2026H\u2014B Interactions in Solution and in the Solid State\u201d Graham, L. A.; Fout, A. R.; Kuehne, K. R.; White, J. L.; Marks, F. M.; Yap, G. P. A.; Zakharov, L. N.; Rheingold, A. L.; Rabinovich, D. Dalton Trans. 2005, 171-180.<\/p>\n
(46) \u201cMediator\u2013Template Assembly of Nanoparticles\u201d Maye, M. M.; Lim, I.\u2011I. S.; Luo, J.; Rab, Z.; Rabinovich, D.; Liu, T.; Zhong, C.\u2011J. J. Am. Chem. Soc. 2005, 127, 1519-1529.<\/p>\n
(47) \u201cFormation of Extended 1D Coordination Polymers in Tetrathioether Complexes of Mercury(II): Effect of the Organic Substituents on the Crystal Structures of {Si(CH2SR)4}HgBr2 (R = Me, Ph)\u201d Peindy, H. N.; Guyon, F.; Knorr, M.; Smith, A. B.; Farouq, J. A.; Islas, S. A.; Rabinovich, D.; Golen, J. A.; Strohmann, C. Inorg. Chem. Commun. 2005, 8, 479-482.<\/p>\n
(48) \u201cTris(mercaptoimidazolyl)borate Complexes of the Coinage Metals: Syntheses and Molecular Structures of the First Gold Compounds and Related Copper and Silver Derivatives\u201d Patel, D. V.; Mihalcik, D. J.; Kreisel, K. A.; Yap, Glenn P. A.; Zakharov, L. N.; Kassel, W. S.; Rheingold, A. L.; Rabinovich, D. Dalton Trans. 2005, 2410-2416.<\/p>\n
(49) \u201cPoly(mercaptoimidazolyl)borate Complexes of Cadmium and Mercury\u201d Rabinovich, D. Struct. Bond. 2006, 120, 143-162.<\/p>\n
(50) \u201c[Bis(3\u2011methyl\u20112-thioxo\u20112,3\u2011dihydro\u20111H\u2011imidazolyl)borato\u2011k2S,S\u2019]dibromoindium(III)\u201d Hill, S. C.; Jones, D. S.; Rabinovich, D. Acta Crystallogr. 2006, E62, m702-m704.<\/p>\n
(51) \u201cGrowth and Optical Properties of Wurtzite-Type CdS Nanocrystals\u201d Cao, H.; Wang, G.; Zhang, S.; Zhang, X.; Rabinovich, D. Inorg. Chem. 2006, 45, 5103-5108.<\/p>\n
(52) \u201cGold(I) Tris(mercaptoimidazolyl)borate Chemistry: Synthesis and Molecular Structure of the First Trinuclear TmR Complex of a Transition Metal\u201d Patel, D. V.; Kreisel, K. A.; Yap, G. P. A.; Rabinovich, D. Inorg. Chem. Commun. 2006, 9, 748-750.<\/p>\n
(53) \u201cGeneration and Optical Properties of Monodisperse Wurtzite-Type ZnS Microspheres\u201d Wu, Q.; Cao, H.; Zhang, S.; Zhang, X.; Rabinovich, D. Inorg. Chem. 2006, 45, 7316-7322.<\/p>\n
(54) \u201cGeneral Classification of Organometallic Reactions\u201d Rabinovich, D. In Comprehensive Organometallic Chemistry III; Crabtree, R. H., Mingos, D. M. P., Eds.; Elsevier: Oxford, 2007; Vol. 1, Chapter 1.03, pp 93-118.<\/p>\n
(55) \u201cNickel Nitrosyl Complexes in a Sulfur-Rich Environment: the First Poly(mercapto-imidazolyl)borate Derivatives\u201d Maffett, L. S.; Gunter, K. L.; Kreisel, K. A.; Yap, G. P. A.; Rabinovich, D. Polyhedron 2007, 26, 4758-4764.<\/p>\n
(56) \u201cLead(II) in a Sulfur-Rich Environment: Synthesis and Molecular Structure of the First Dinuclear Bis(mercaptoimidazolyl)methane Complex\u201d Pinder, T. A.; VanDerveer, D.; Rabinovich, D. Inorg. Chem. Commun. 2007, 10, 1381-1384.<\/p>\n
(57) \u201cFemtosecond Isomerization in a Photochromic Molecular Switch\u201d Mockus, N. V.; Rabinovich, D.; Petersen, J. L.; Rack, J. J. Angew. Chem. Int. Ed., in press.<\/p>\n
Last updated: 19 December 2007<\/em><\/p>\n","protected":false},"excerpt":{"rendered":" A. Columbia University (1989-1994) (1) \u201cHexakis(trimethylphosphine)tungsten(0): Synthesis, Structure, and Reactivity\u201d Rabinovich, D.; Parkin, G. J. Am. Chem. Soc. 1990, 112, 5381-5383. (2) \u201cCompetitive sp3 and sp2 C-H Bond Activation of Phenols by W(PMe3)6 and W(PMe3)4(h2-CH2PMe2)H: Formation of Four- and Five-Membered Oxametallacycles\u201d Rabinovich, D.; Zelman, R.; Parkin, G. J. Am. Chem. Soc. 1990, 112, 9632-9633. (3) […]<\/p>\n","protected":false},"author":581,"featured_media":0,"parent":21,"menu_order":10,"comment_status":"closed","ping_status":"closed","template":"","meta":{"jetpack_post_was_ever_published":false,"footnotes":""},"class_list":["post-92","page","type-page","status-publish","hentry"],"jetpack_shortlink":"https:\/\/wp.me\/P2UM4X-1u","jetpack_sharing_enabled":true,"_links":{"self":[{"href":"https:\/\/pages.charlotte.edu\/daniel-rabinovich\/wp-json\/wp\/v2\/pages\/92","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/pages.charlotte.edu\/daniel-rabinovich\/wp-json\/wp\/v2\/pages"}],"about":[{"href":"https:\/\/pages.charlotte.edu\/daniel-rabinovich\/wp-json\/wp\/v2\/types\/page"}],"author":[{"embeddable":true,"href":"https:\/\/pages.charlotte.edu\/daniel-rabinovich\/wp-json\/wp\/v2\/users\/581"}],"replies":[{"embeddable":true,"href":"https:\/\/pages.charlotte.edu\/daniel-rabinovich\/wp-json\/wp\/v2\/comments?post=92"}],"version-history":[{"count":6,"href":"https:\/\/pages.charlotte.edu\/daniel-rabinovich\/wp-json\/wp\/v2\/pages\/92\/revisions"}],"predecessor-version":[{"id":112,"href":"https:\/\/pages.charlotte.edu\/daniel-rabinovich\/wp-json\/wp\/v2\/pages\/92\/revisions\/112"}],"up":[{"embeddable":true,"href":"https:\/\/pages.charlotte.edu\/daniel-rabinovich\/wp-json\/wp\/v2\/pages\/21"}],"wp:attachment":[{"href":"https:\/\/pages.charlotte.edu\/daniel-rabinovich\/wp-json\/wp\/v2\/media?parent=92"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}