{"id":11,"date":"2012-09-07T10:50:06","date_gmt":"2012-09-07T14:50:06","guid":{"rendered":"http:\/\/pages.charlotte.edu\/schmedake-research\/?page_id=11"},"modified":"2025-01-24T14:16:45","modified_gmt":"2025-01-24T19:16:45","slug":"publications","status":"publish","type":"page","link":"https:\/\/pages.charlotte.edu\/schmedake-research\/publications\/","title":{"rendered":"Publications"},"content":{"rendered":"
\n

Ye, T., Sun, Y.-Y., Kocherga, M., Nesmelov, A., Schmedake, T.A. and Zhang, Y. Degradation Kinetics of Organic\u2013Inorganic Hybrid Materials from Micro-Raman Spectroscopy and Density-Functional Theory: The Case of \u03b2<\/i>-ZnTe(en)0.5<\/sub>. Small<\/em> 2023<\/strong>, 2302935.\u00a0https:\/\/doi.org\/10.1002\/smll.202302935<\/a><\/p>\n

Shibu, A.; Jones, S.; Tolley, P.; Diaz, D.; Kwiatkowski, C.; Jones, D.; Shivas, J.; Foley, J.; Schmedake, T.; Walter, M. Correlating structure and photophysical properties in thiazolo[5,4-d]thiazole crystal derivatives for use in solid-state photonic and fluorescence-based optical devices.\u00a0Materials Advances <\/i>2023<\/b>,\u00a04<\/i>\u00a0(23), 6321-6332. DOI: 10.1039\/d3ma00686g<\/a>.<\/p>\n

Brotherton, A. R.<\/span>,\u00a0Shibu, A.<\/span>,\u00a0Meadows, J. C.<\/span>,\u00a0Sayresmith, N. A.<\/span>,\u00a0Brown, C. E.<\/span>,\u00a0Ledezma, A. M.<\/span>,\u00a0Schmedake, T. A.<\/span>,\u00a0Walter, M. G.<\/span>,\u00a0Leveraging Coupled Solvatofluorochromism and Fluorescence Quenching in Nitrophenyl-Containing Thiazolothiazoles for Efficient Organic Vapor Sensing<\/span>.\u00a0Adv. Sci.<\/i>\u00a02023<\/span><\/strong>,\u00a010<\/span>, 2205729.\u00a0https:\/\/doi.org\/10.1002\/advs.202205729<\/a><\/p>\n

Peloquin, D.M.; Bimukhanov, A.N.; Aldongarov, A.A.; Merkert, J.W.; Donovan-Merkert, B.T.; Schmedake, T.A. Spectroelectrochemical and Theoretical Study of [Si(ttpy)2<\/sub>](PF6<\/sub>)4<\/sub>: A Potential Polychromatic Electrochromic Dye.\u00a0Molecules<\/em>\u00a02022<\/b>,\u00a027<\/em>, 8521. https:\/\/doi.org\/10.3390\/molecules27238521<\/a><\/p>\n

Kocherga, M.; Boyle, K. M.; Merkert, J.; Schmedake, T. A.; Walter, M. G.; Exploring the molecular electronic device applications of synthetically versatile silicon pincer complexes as charge transport and electroluminescent layers. Mater. Adv., 2022<\/strong>, 3<\/em>, 2373-2379. https:\/\/doi.org\/10.1039\/D1MA00737H<\/a><\/p>\n

Earnhardt, A. W.; Boyle, K. M.; Adams, T.; Walter, M. G.; Wang, Y.; Zhang, Y.; Adeyemi, A.; Merkert, J.; Bimukhanov, A. N.; Aldongarov, A. A.; et al. Bipolar charge transport in a robust hexacoordinate organosilane.\u00a0Journal of Organometallic Chemistry\u00a0<\/i>2022<\/b>,\u00a0961<\/i>, 122208. https:\/\/doi.org\/10.1016\/j.jorganchem.2021.122208<\/a><\/p>\n

Ye, T; Kocherga, M.; Sun, Y.-Y.; Nesmelov, A.; Zhang, F.; Oh, W.; Huang, X.-Y.; Li, J.; Beasock, D.; Jones, D.S.; Schmedake, T.A.; Zhang, Y.; II\u2013VI Organic\u2013Inorganic Hybrid Nanostructures with Greatly Enhanced Optoelectronic Properties, Perfectly Ordered Structures, and Shelf Stability of Over 15 Years, <\/span>ACS Nano<\/i><\/span>\u00a02021<\/span><\/strong>, 15 (<\/em>6)<\/span>, 10565\u20131057.<\/span><\/span>\u00a0<\/span>https:\/\/doi.org\/10.1021\/acsnano.1c03219<\/a><\/p>\n<\/div>\n

Nesmelov, A.; Lee, D.; Bejger, C.; Kocherga, M.; Lyles, Z.; Greenier, M.K.; Vitallo, A.A.; Kaouk, G.; Jones, D.S.; Schmedake, T.A. Accessing new microporous polyspirobifluorenes via a C\/Si switch. Chem. <\/em>Commun. <\/em>2020<\/strong>, 56<\/em>, 9846 – 9849. <\/em><\/p>\n

Li, Y. Z.; Kocherga, M.; Park, S.; Lata, M.; McLamb, M.; Boreman, G.; Schmedake, T. A.; Hofmann, T., Optical dielectric function of Si(2,6-bis(benzimidazol-2 ‘-yl)pyridine)(2) determined by spectroscopic ellipsometry.\u00a0Optical Materials Express\u00a0<\/em>2019, <\/strong>9<\/em>\u00a0(8), 3469-3475.<\/p>\n

Bimukhanov, A.N.; Aldongarov, A.A.; Schmedake, T.A. DFT calculation of optical properties of new neutral hexacoordinated Si(bzimpy)2 complexes. Eurasian Journal of Physics and Functional Materials, <\/em>2019<\/strong>, 3<\/em>(2), 183-190.<\/p>\n

Kocherga, M.; Castaneda, J.; Walter, M. G.; Zhang, Y.; Saleh, N. A.; Wang, L.; Jones, D. S.; Merkert, J.; Donovan-Merkert, B.; Li, Y. Z.; Hofmann, T.; Schmedake, T. A., Si(bzimpy)2 – a hexacoordinate silicon pincer complex for electron transport and electroluminescence.\u00a0Chem. Commun.<\/i>\u00a02018<\/b>,\u00a054<\/i>\u00a0(100), 14073-14076.<\/p>\n

Lee, D. A.; Peloquin, D. M.; Yapi, E. W.; McMinn, L. A.; Merkert,J. W.; Donovan-Merkert, B. T.; Vitallo, A. A.; Peterson, A. R.; Jones, D.S.; Ceccarelli, C.; Schmedake, T. A., \u201cTetramethylsilanoviologen\u201d: Synthesis, characterization, and hydrolysis of a silolodipyridinium ion. Polyhedron<\/em> 2017<\/strong>, 133<\/em>, 358-363.<\/p>\n

Peloquin, D. M.; Schmedake, T. A., Recent advances in hexacoordinate silicon with pyridine-containing ligands: Chemistry and emerging applications.\u00a0 Coordination Chemistry Reviews <\/em>2016<\/strong>, 323, <\/em>107.<\/p>\n

Peloquin, D. M.; Dewitt, D. R.; Patel, S. S.; Merkert, J. W.; Donovan-Merkert, B. T.; Schmedake, T. A., Spectroelectrochemistry of tris(bipyridyl)silicon(IV): ligand localized reductions with potential electrochromic applications. Dalton Transactions <\/i>2015,<\/b> 44<\/i> (43), 18723-18726.<\/p>\n

Maguylo, C.; Chukwu, C.; Aun, M.; Monroe, B.; Ceccarelli, C.; Jones, D. S.; Merkert, J. W.; Donovan-Merkert, B. T.; Schmedake, T. A., Exploring the structure and redox activity of hexacoordinate bis(bipyridyl)silicon(IV) complexes. Polyhedron <\/i>2015,<\/b> 94<\/i>, 52-58.<\/p>\n

Nurakhmetov, T. N.; Kuterbekov, K. A.; Daurenbekov, D. H.; Zhanbotin, A. Z.; Betekbaev, A. A.; Kainarbay, A. Z.; Schmedake, T. A.; Kuterbekov, M. K., Solar Radiation Conversion With Mesoporous Silica Activated by Rare-Earth Ions. Journal of Solar Energy Engineering-Transactions of the ASME <\/i>2015,<\/b> 137<\/i> (6).<\/p>\n

Lee, D. A.; Moon, S. K.; Sizeland, A. N.; Gould, N. W.; Gbarbea, E. M.; Owusu, D.; Jones, D. S.; Schmedake, T. A., Synthesis and Characterization of a Dipyridocatecholate Silicon Complex, Inorganic Chemistry Communications <\/i>2013,<\/b> 33<\/i> (0), 125-128.<\/p>\n

Nurakhmetov, T. N.; Kuterbekov, K. A.; Schmedake, T. A.; Zhanbotin, A.; Kainarbay, A.; Salihodja, J. M.; Zhunusbekov, A. M.; Pazylbek, S.; Bekmyrza, K.; Daurenbekov, D.; Baitemirova, A., Luminescent materials based on nanoparticles of silicon dioxide for solar cells. In International Conference on Functional Materials and Nanotechnologies 2013<\/i>, Brik, M.; Zazubovits, S.; Kikas, A.; Parna, R., Eds. 2013<\/strong>; Vol. 49.<\/p>\n

Alston, J. R.; Brokaw, D.; Overson, C.; Schmedake, T. A.; Poler, J. C., Hybrid SWCNT – NiO composites for supercapacitor applications. MRS Online Proc. Libr. <\/i>2013,<\/b> 1552<\/i> (Nanostructured Metal Oxides for Advanced Applications), opl.2013.624, 7 pp.<\/p>\n

Suthar, B.; Aldongarov, A.; Irgibaeva, I. S.; Moazzen, M.; Donovan-Merkert, B. T.; Merkert, J. W.; Schmedake, T. A., Electrochemical and spectral properties of hexacoordinate polypyridyl silicon complexes. Polyhedron <\/em>2012,<\/strong> 31<\/em> (1), 754-758.<\/p>\n

Zhanbotin, A.; Soriano, R. B.; Ikonen, A. K.; Nurakhmetov, T. N.; Schmedake, T. A., Luminescent Mesoporous Colloidal Silica: A Nanoporous Substrate For Photosensitization Of Lanthanide Ions. Materials Letters <\/em>2011,<\/strong> 65<\/em> (1), 10-12.<\/p>\n

Liu, K.; Schmedake, T. A.; Tsu, R., Experimental determination of the band structure of photonic crystals of colloidal silica spheres. Physics Letters A<\/em> 2009<\/strong>, 373 (21), 1885-1890.<\/p>\n

Zhanbotin, A.; Nurakhmetov, T.N.; Schmedake, T.A., Chemistry And Optical Properties Of Luminescent Mesoporous Colloidal Silica. Russian Physics Journal<\/em> 2009<\/strong>, 52, Number 8\/2, 369-372<\/p>\n

Irgibaeva, I.; Aldongarov, A.; Barashkov, N.; Schmedake, T., Study of Spectral Properties of Bis (1,10-phenanthroline) Silicon Hexacoordinated Complexes by Density Functional Theory. International Journal of Quantum Chemistry <\/em>2008<\/strong>, 108, (14), 2641-2647.
\n\u00a0<\/em>
\nLiu, K.; Schmedake, T. A.; Tsu, R., A comparative study of colloidal silica spheres: Photonic crystals versus Bragg’s law. Physics Letters A <\/em>2008<\/strong>, 372, (24), 4517-4520.<\/p>\n

Soriano, R. B.; Kpatcha, E.; Jakob, A. M.; Merkert, J. W.; Carlin, C. M.; Schmedake, T. A. Long life-time emission in luminescent colloidal silica. \u00a0Applied Physics Letters<\/em> 2007<\/strong>, 91, 091909.<\/p>\n

Liu, K.; Schmedake, T. A.; Daneshvar, K.; Tsu, R., Interaction of CdSe\/ZnS quantum dots: Among themselves and with matrices. Microelectronics Journal <\/em>2007,<\/strong> 38, (6-7), 700-705.<\/p>\n

Poler, J.;\u00a0 Donovan-Merkert, B.T.;\u00a0 Davies, A.;\u00a0 El-Kouedi, M.;\u00a0 Krueger, J.;\u00a0 Smith, S.;\u00a0 Stokes, E.; and Schmedake, T. A.\u00a0 \u201cEfforts to Implement a PhD degree program in Nanoscale Science at UNC Charlotte\u201d, in Education in Nanoscience and Engineering<\/em>, edited by R. Carpenter, S. Seal, N. Healy, N. Shinn, W. Braue (Mater. Res. Soc. Symp. Proc. 931E, Warrendale, PA, 2006<\/strong>), p. 0931-KK04-04.<\/p>\n

Jakob, A. M.; Schmedake, T. A., A novel approach to monodisperse, luminescent silica spheres. Chemistry of Materials <\/em>2006<\/strong>, 18, (14), 3173-3175.<\/p>\n

Poler, J. C.; Schmedake, T. A.; Ye, W., Cross-sectional AFM study of etching kinetics of oxidized porous silicon. Physica Status Solidi A: Applied Research <\/em>2004<\/strong>, 201, (4), 756-761.<\/p>\n

Leites, L. A.; Bukalov, S. S.; Mangette, J. E.; Schmedake, T. A.; West, R., 80Conformational polymorphism of solid tetramesityldisilene Mes2Si:SiMes2 (Raman, UV-vis, IR and fluorescence study). Spectrochimica Acta, Part A: Molecular and Biomolecular Spectroscopy <\/em>2003<\/strong>, 59A, (9), 1975-1988.<\/p>\n

Cunin, F.; Schmedake, T. A.; Link, J. R.; Li, Y. Y.; Koh, J.; Bhatia, S. N.; Sailor, M. J., Biomolecular screening with encoded porous-silicon photonic crystals. Nature Materials <\/em>2002<\/strong>, 1, (1), 39-41.<\/p>\n

Liu, R.; Schmedake, T. A.; Li, Y. Y.; Sailor, M. J.; Fainman, Y., Novel porous silicon vapor sensor based on polarization interferometry. Sensors and Actuators, B: Chemical <\/em>2002<\/strong>, B87, (1), 58-62.<\/p>\n

Schmedake, T. A.; Cunin, F.; Link, J. R.; Sailor, M. J., Standoff detection of chemicals using porous silicon “smart dust” particles. Advanced Materials (Weinheim, Germany) <\/em>2002<\/strong>, 14, (18), 1270-1272.<\/p>\n

Schmedake, T. A.; Haaf, M.; Paradise, B. J.; Millevolte, A. J.; Powell, D. R.; West, R., Electronic and steric properties of stable silylene ligands in metal(0) carbonyl complexes. Journal of Organometallic Chemistry <\/em>2001<\/strong>, 636, (1-2), 17-25.<\/p>\n

West, R.; Schmedake, T. A.; Haaf, M.; Becker, J.; Mueller, T., A disilanyl dianion and a silyl dianion from a stable silylene. Chemistry Letters <\/em>2001<\/strong>, (1), 68-69.<\/p>\n

Haaf, M.; Schmedake, T. A.; Paradise, B. J.; West, R., Synthesis and reactivity of the stable silylene N,N’-di-tert-butyl-1,3-diaza-2-sila-2-ylidene. Canadian Journal of Chemistry <\/em>2000<\/strong>, 78, (11), 1526-1533.<\/p>\n

Schmedake, T. A.; Haaf, M.; Paradise, B. J.; Powell, D.; West, R., Two Trigonal Ni(silylene)3 Complexes. Organometallics <\/em>2000<\/strong>, 19, (17), 3263-3265.<\/p>\n

Haaf, M.; Schmedake, T. A.; West, R., Stable Silylenes. Accounts of Chemical Research <\/em>2000<\/strong>, 33, (10), 704-714.<\/p>\n

Schmedake, T. A.; Haaf, M.; Apeloig, Y.; Mueller, T.; Bukalov, S.; West, R., Reversible Transformation between a Diaminosilylene and a Novel Disilene. Journal of the American Chemical Society <\/em>1999<\/strong>, 121, (40), 9479-9480.<\/p>\n

Haaf, M.; Schmiedl, A.; Schmedake, T. A.; Powell, D. R.; Millevolte, A. J.; Denk, M.; West, R., Synthesis and Reactivity of a Stable Silylene. Journal of the American Chemical Society <\/em>1998<\/strong>, 120, (49), 12714-12719.<\/p>\n

Leites, L. A.; Bukalov, S. S.; Mangette, J. E.; Schmedake, T. A.; West, R., Raman and UV-Vis study of the conformational polymorphism of solid tetramesityldisilene Mes2Si:SiMes2. Mendeleev Communications <\/em>1998<\/strong>, (2), 43-44.<\/p>\n

Schmedake, T. A.; Welch, L. E., The quantitative analysis of an analgesic tablet: an NMR experiment for the instrumental analysis course. Journal of Chemical Education <\/em>1996<\/strong>, 73, (11), 1045-1048.
\n\u00a0<\/strong><\/p>\n","protected":false},"excerpt":{"rendered":"

Ye, T., Sun, Y.-Y., Kocherga, M., Nesmelov, A., Schmedake, T.A. and Zhang, Y. Degradation Kinetics of Organic\u2013Inorganic Hybrid Materials from Micro-Raman Spectroscopy and Density-Functional Theory: The Case of \u03b2-ZnTe(en)0.5. Small 2023, 2302935.\u00a0https:\/\/doi.org\/10.1002\/smll.202302935 Shibu, A.; Jones, S.; Tolley, P.; Diaz, D.; Kwiatkowski, C.; Jones, D.; Shivas, J.; Foley, J.; Schmedake, T.; Walter, M. Correlating structure and […]<\/p>\n","protected":false},"author":21,"featured_media":0,"parent":0,"menu_order":2,"comment_status":"closed","ping_status":"closed","template":"","meta":{"jetpack_post_was_ever_published":false,"footnotes":""},"class_list":["post-11","page","type-page","status-publish","hentry"],"jetpack_shortlink":"https:\/\/wp.me\/P2I6ni-b","jetpack_sharing_enabled":true,"_links":{"self":[{"href":"https:\/\/pages.charlotte.edu\/schmedake-research\/wp-json\/wp\/v2\/pages\/11","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/pages.charlotte.edu\/schmedake-research\/wp-json\/wp\/v2\/pages"}],"about":[{"href":"https:\/\/pages.charlotte.edu\/schmedake-research\/wp-json\/wp\/v2\/types\/page"}],"author":[{"embeddable":true,"href":"https:\/\/pages.charlotte.edu\/schmedake-research\/wp-json\/wp\/v2\/users\/21"}],"replies":[{"embeddable":true,"href":"https:\/\/pages.charlotte.edu\/schmedake-research\/wp-json\/wp\/v2\/comments?post=11"}],"version-history":[{"count":25,"href":"https:\/\/pages.charlotte.edu\/schmedake-research\/wp-json\/wp\/v2\/pages\/11\/revisions"}],"predecessor-version":[{"id":234,"href":"https:\/\/pages.charlotte.edu\/schmedake-research\/wp-json\/wp\/v2\/pages\/11\/revisions\/234"}],"wp:attachment":[{"href":"https:\/\/pages.charlotte.edu\/schmedake-research\/wp-json\/wp\/v2\/media?parent=11"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}